Degradation of natural organic matter and disinfection byproducts formation by solar photolysis of free available chlorine.

Environment disinfection effectively curbs transmission of the Severe Acute Respiratory Syndrome Coronavirus-2 (SARS-CoV-2). However, elevated concentration of free available chlorine (FAC) in disinfectants can be discharged into surface water, generating toxic disinfection byproducts (DBPs). The impact of solar photolysis of FAC on natural organic matter (NOM) to form DBPs has not been well studied. In this work, solar photolysis of FAC was found to result in higher formation of DBPs, DBPs formation potential (DBPsFP), total organic chlorine (TOCl) and lower specific ultraviolet absorbance at 254 nm (SUVA254), compared to dark chlorination. In solar photolysis of FAC, formation of total DBPs was promoted by pH=8, but hindered by the addition of HCO3-, radical scavenger or deoxygenation, while addition of NO3-and NH4+both enhanced the formation of nitrogenous DBPs. Differences in the formation of DBPs in solar photolysis of FAC under various conditions were influenced by reactive species. The formation of trichloromethane (TCM) and haloacetic acids (HAAs) in solar photolysis of FAC positively correlated with the steady-state concentrations of ClO• and O3. The steady-state concentrations of •NO and •NH2 positively correlated with the formation of halonitromethanes (HNMs). HAAs and haloacetonitriles (HANs) mainly contributed to calculated cytotoxicity of DBPs. This study demonstrates that solar photolysis of FAC may significantly impact the formation of DBPs in surface water due to extensive use of disinfectants containing FAC during SARS-CoV-2 pandemic.

Correlation between BOD/COD Ratio and Octanol/Water Partition Coefficient for Mixture Organic Compounds

Correlation between the BOD/COD ratio and Partition coefficient of octanol/ water (Pow) on a single organic substance shows that the Pow value is directly proportional to the toxicity level and inversely proportional to BOD/COD ratio. This research examined the correlation to a mixture of organic substances. The objective is to obtain a varied range of substances, as well as determining the quality of wastewater discharging to fresh waters. Need for analysis of organic substances used as antiseptics during the Covid-19 pandemic. In addition, organic substances from the organophosphate pesticide class, diazinon, were used. BOD5, COD, Pow, and LC50-96h toxicity tests using Daphnia magna were used. Six types of the mixture of organic substances included diazinon-formaldehyde-isopropyl alcohol, ethanol-oxalic acid-formaldehyde, isopropyl alcohol-glycerol-lactose, acetic acid-isopropyl alcohol-formaldehyde, sucrose-glycerol-acetic acid, and oxalic acid-formaldehyde-diazinon, with 3 different concentrations of 10, 100, and 1000 mg/L, three repetitions. The lowest BOD/COD ratio (<0.2) and the highest Pow value (>4) are found in diazinon-formaldehyde-IPA. Its toxicity in D. magna also showed the lowest LC-50 (11.82 mg/L). Whereas, sucrose-glycerol-acetic acid had the highest BOD/COD ratio (>0.7) and lowest Pow (<0.7) with the highest LC-50 (567.88 mg/L). Other organic substances mixtures have characteristics in the range of these mixtures. Pow variability and the BOD/COD ratio have a negative correlation. A mixture of organic matter is more biodegradable making it has a higher tendency to dissolve in water.Copyright © 2022 Informatics Publishing Limited and The Society of Toxicology. All rights reserved.

Effective multipurpose sewage sludge and food waste reduction strategies: A focus on recent advances and future perspectives

Energy crisis and increasing rigorous management standards pose significant challenges for solid waste management worldwide. Several emerging diseases such as COVID-19 aggravated the already complex solid waste management crisis, especially sewage sludge and food waste streams, because of the increasingly large production year by year. As mature waste disposal technologies, landfills, incineration, composting, and some other methods are widespread for solid wastes management. This paper reviews recent advances in key sewage sludge disposal technologies. These include incineration, anaerobic digestion, and valuable products oriented-conversion. Food waste disposal technologies comprised of thermal treatment, fermentation, value-added product conversion, and composting have also been described. The hot topic and dominant research foci of each area are summarized, simultaneously compared with conventional technologies in terms of organic matter degradation or conversion performance, energy generation, and renewable resources production. Future perspectives of each technology that include issues not well understood and predicted challenges are discussed with a positive effect on the full-scale implementation of the discussed disposal methods. © 2022 Elsevier Ltd

Survivability and Benefit Evaluation of Streptomyces sp. and Trichoderma sp. as Active Ingredients of Biopesticides and Soil Fertility Enhancer in Shallot Fields at Wates Village Tulungagung

The purpose of research on the Farmer Empowerment Program in Wates Village is to increase knowledge in the field of sustainable agriculture and transfer of technology for the application of biopesticides containing the Biological Control Agent (APH) Streptomyces sp., Trichoderma sp. combined with shallot cultivation technology in the village of Wates Tulungagung. Innovative methods and Participatory Action Research (PAR) are used to encourage transformative action, by involving community members as PAR implementers in describing the types of plants being treated and applying them during the Covid-19 pandemic in the Wates village, Tulungagung District. The results of the evaluation and monitoring of the use of APH as a biopesticide and fungicide to control moler disease caused a decrease in the population of microorganisms, the population of Trichoderma sp. was absent (o) but Streptomyces sp. increase. Giving APH proved that microorganisms act as decomposers that increase the availability of N and P nutrients through their ability to accelerate the decomposition of organic matter given at the beginning of planting. The K nutrient content in the soil before and after treatment did not differ.

The impact of disposable mask waste pollution in peat soil

The abundance of plastic waste in Indonesia has increased due to the contribution of disposable masks waste during the COVID-19 pandemic. The improper waste management causes the habit of dumping waste in the soil system to still frequently occur. The secondary microplastics from disposable mask waste has the potential to damage soil quality and soil capillary water. Therefore, this study was conducted with the aim of understanding the effects of disposable mask waste in peat soil. The research was conducted by setting up 3 reactors containing peat soil with disposable mask waste buried in it and some plants being grown on it. For 45 days, observations and samples were taken, both filtrate water and soil for analysis. The analysis results showed significant changes in soil properties with changes in the concentration of inorganic matter, organic matter, porosity, bulk density, and water content. Further research needs to be done to see the effects of disposable mask waste in the soil system in real conditions where several confounding variables cannot be controlled.

Chemical characteristics and sources of PM2.5 in Hohhot, a semi-arid city in northern China: insight from the COVID-19 lockdown

A knowledge gap exists concerning how chemical composition and sources respond to implemented policy control measures for aerosols, particularly in a semi-arid region. To address this, a single year's offline measurement was conducted in Hohhot, a semi-arid city in northern China, to reveal the driving factors of severe air pollution in a semi-arid region and assess the impact of the COVID-19 lockdown measures on chemical characteristics and sources of PM2.5. Organic matter, mineral dust, sulfate and nitrate accounted for 31.5 %, 14.2 %, 13.4 % and 12.3 % of the total PM2.5 mass, respectively. Coal combustion, vehicular emission, crustal source and secondary inorganic aerosols were the main sources of PM2.5 in Hohhot, at 38.3 %, 35.0 %, 13.5 %, and 11.4 %, respectively. Due to the coupling effect of emission reduction and improved atmospheric conditions, the concentration of secondary inorganic components, organic matter and elemental carbon declined substantially from the pre-lockdown (pre-LD) period to the lockdown (LD) and post-lockdown (post-LD) periods. The source contribution of secondary inorganic aerosols increased (from 21.1 % to 37.8 %), whereas the contribution of vehicular emission reduced (from 35.5 % to 4.4 %) due to lockdown measures. The rapid generation of secondary inorganic components caused by unfavorable meteorological conditions during lockdown led to serious pollution. This study elucidates the complex relationship between air quality and environmental policy.

Removal and toxic forecast of microplastics treated by electrocoagulation: Influence of dissolved organic matter.

In recent years, the break of COVID-19 makes the large use of disposable products, which causes the removal of microplastics become an imperative problem. Electrocoagulation is one of the effective removal technologies, but there is hardly research concentrating on the effect of substrate in the actual water on the microplastics removal with electrocoagulation. As an important role of water bodies, dissolved organic matter (DOM) has a vital and inevitable effect on the efficiency of electrocoagulation. In this study, the effect of DOM in tailwater on microplastics during electrocoagulation is elucidated by comparing the electrocoagulation treatment results between simulated wastewater and tailwater, using parallel factor analysis (PARAFAC), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectrometer (FTIR) and zeta potential analyzer. Three kinds of microplastic particles (i.e. polypropylene, polyethylene, and polymethyl methacrylate) were added into each of the two kinds of wastewaters to form six electrocoagulation systems. Results show that DOM in tailwater promotes the production of flocs and free radicals during electrocoagulation process. Fe2+ and Fe3+ are adsorbed on the surface of DOM molecules and combined with •OH form flocs. Although DOM accelerates the production of free radicals and thus promotes the aging of microplastics, flocs with DOM as crystal nucleus can prevent toxic substances and small-sized microplastics from leaching into water again. Therefore, electrocoagulation is preferred to removal microplastics in water with high concentration of DOM. This study provides a significant reference for microplastics removal by electrocoagulation in actual water, and promote the practical application of electrocoagulation for microplastics removal in water treatment.

Direct Sunlight Driven In2S3 Thin Film Based Water Treatment Proto-Type

A multi-faceted energy intensive technology that can be used for water disinfection and synthesis of electrolysed water (EW) is the need of the hour to achieve a sustainable post COVID 19 water management strategy. Direct sunlight driven processes are legislatively green technologies and hold the key in environmental sustenance. The development of a laboratory proto type reactor powered by a photovoltaic module for the treatment open source river water is described in this paper. This paper reports on the efficacy of the developed proto type technology for multipurpose application namely: (1) the production of Electrolysed water (EW) in a cost efficient manner using direct sunlight and (2) the removal of organic impurity from water using direct sunlight without the use of any photo catalyst or membrane. The prototype reactor utilizes chemical spray pyrolysis deposited highly photo-conducting indium sulphide thin films grown on fluorine doped tin oxide (F:SnO2) substrate (coated using chemical spray pyrolysis technique in-house) as the photo electrode. Dissolved organic matter arising in river water has distinctive fluorescence properties, and this research has utilized it to identify dissolved organic substances in both random samples and treated water. The work proves that photovoltaic module powered electrolytic reactors consisting of In2S3 electrodes can be used for treatment of river water. A diaphragm free, energy intensive route for the production of electrolysed water with the use of non-hazardous NaCl as the electrolyte has been demonstrated here. We conclude that In2S3 electrodes can be used for non-photo catalytic reduction of humic-derived impurities in river water. These results are also encouraging on the prospects of treating Nitrates present in the river water. The likes of techniques as described in this report that do not use photo catalyst or membranes may pave way for real time photovoltaic module powered floating reactors that can decontaminate water bodies on a large scale. The technique used by us demonstrates that a chlorine free route can be optimized for the synthesis of EW eliminating the production of large amounts of wastewater with high levels of biological oxygen demand (BOD).

The Influence of Municipal Wastewater Treatment Technologies on the Biological Stabilization of Sewage Sludge: A Systematic Review

Various wastewater treatment technologies are available today and biological processes are predominantly used in these technologies. Increasing wastewater treatment systems produces large amounts of sewage sludge with variable quantities and qualities, which must be properly managed. Anaerobic and aerobic digestion and composting are major strategies to treat this sludge. The main indicators of biological stabilization are volatile fatty acids (VFAs), volatile solids (VS), the carbon/nitrogen (C/N) ratio, humic substances (HS), the total organic carbon (TOC), the carbon dioxide (CO2) evolution rate, the specific oxygen uptake rate (SOUR), and the Dewar test;however, different criteria exist for the same indicators. Although there is no consensus for defining the stability of sewage sludge (biosolids) in the research and regulations reviewed, controlling the biological degradation, vector attraction, and odor determines the biological stabilization of sewage sludge. Because pollutants and pathogens are not completely removed in biological stabilization processes, further treatments to improve the quality of biosolids and to ensure their safe use should be explored.

Non-targeted characterization of dissolved organic matter from a wastewater treatment plant by FT-ICR-MS: A case study of hospital sewage

Hospitals generate large volumes of wastewater. Dissolved organic matter (DOM) in wastewater effluent can act as precursors of disinfection by-products, transporter of pollutants, and affect the performance of treatment plants. This study aims to characterize the composition of DOM in medical wastewater and investigate the selectivity of the hospital treatment plant in the removal of DOM. DOM was characterized by Fourier-transform ion-cyclotron resonance mass spectrometry (FT-ICR-MS) and excitation-emission matrix fluorescence spectroscopy (EEMs). DOM of medical wastewater was dominated by aliphatic and highly unsaturated compounds, a feature that is remarkably different from that of natural DOM. In the membrane bioreactor (MBR) unit, more CHNO compounds and highly unsaturated compounds were formed. After disinfection, the highly unsaturated and humic-like compounds were reduced, accompanying a decrease in aromaticity. After reverse osmosis, the highly unsaturated and CHO compounds were concentrated and removed. These steps were complementary in the removal of DOM, suggesting effective transformation and elimination of DOM. This study contributes to a better understanding of the features of DOM in medical wastewater and treatment plant performance in the removal of DOM, which is indispensable for the large-scale design and application of technologies for hospital wastewater treatment, especially in the context of the COVID-19 pandemic.

Biogeochemical and physical linkages between the Arctic Ocean and Sub-Arctic Pacific through marginal seas

Memorial addresses for Mr. Alexey Fedorovich Shcherbinin and Captain Evgeniy Anikovich Sklizkov Mr. Alexey Fedorovich Shcherbinin (who belonged to the Far Eastern Regional Hydrometeorological Research Institute, in Russia) passed away on 27 Nov. 2020 due to the COVID-19 pandemic. Mr. Shcherbinin was a great and respectful person who worked hard to make our re-searchers active in the field through the many research expeditions and international projects conducted thus far, including many Russian and Japanese collaborations. He was a man of the sea who knew the ocean better than anyone else, and he always led us on expeditions to under-stand the ocean with kindness and warmness. We lost another dear friend, the captain Evgeniy Anikovich Sklizkov (who belonged to the Far Eastern Regional Hydrometeorological Research Institute, in Russia). He passed away on 30 Oct. 2018 after the Mu18 expedition. He took us out on the Go11, Mu14, and Mu18 expe-ditions. Without him, we would not have been able to carry out any of our scientific expeditions. He was always calm and collected and made sure that our expeditions were successful. He was also a great leader and a man of the sea who treated us with kindness and warmness. Their professional leadership of scientists and crews during numerous overseas expeditions are deeply engraved in the minds of many researchers. Jun Nishioka, Ichiro Yasuda, Kay I. Ohshima, M. Wakatsuchi, Yuri N. Volkov and all researcher who joined previous Russian and Japanese collaborative expeditions express here our deepest condolences to these men and dedicate this special issue to them to be listed among their achievements.

Responses of regional environmental factors to the reference value of neutrophil-lymphocyte ratio in healthy adults

Objective: This paper screened the factors that may influence the spatial differentiation of Neutrophil-to-lymphocyte ratio (NLR) reference values in healthy adults in China and explored the trend of NLR reference values in China. Methods: For this research, we collected the NLR of 162 681 healthy adults from 62 cities in China. Spearman regression analysis was used to analyze the correlation between NLR and 25 geography secondary indexes. We extracted 9 indexes with significant correlation, built a random forest (RF) model, and predicted the country's urban healthy adults' NLR reference value. By using the disjunctive Kriging method, we obtained the geographical distribution of NLR reference value of healthy adults in China. Results: The reference value of NLR of healthy adults in China was significantly correlated with the 9 secondary indexes, namely, altitude, sunshine duration, annual average temperature, annual average relative humidity, annual temperature range, annual average wind speed, content of organic matter in topsoil, cation exchange capacity in topsoil (clay), and total amount of CaSO4 in soil. The geographical distribution of NLR values of healthy adults in China showed a trend of being higher in Southeast China and lower in Northwest China, higher in coastal areas and lower in inland areas. Conclusion: This study lays a foundation for further research on the mechanism of different influencing factors on the reference value of NLR index. A random forest model composed of significant influencing factors has been established to provide the basis for formulating reference criteria for the prognostic factors of the novel coronavirus using NLR reference values in different regions.

Valorization of Quality of Vermicomposts and Composts Using Various Parameters

Due to the increasing biomass of biowaste it is necessary to manage it rationally. This work presents comparisons and valorization of vermicomposts (VCs) and composts (Cs) prepared from various biowastes generated in households and private gardens, in terms of their practical use. The tested VCs and Cs were subjected to chemical analyses to assess the amounts of macro- (N, P, K, S, Mg, Ca, Na) and micronutrients (Fe, Zn, Mn, Cu, Ni), as well as contents of organic matter (OM), total organic carbon (TOC), humic compounds (HS) and labile and water extractable organic carbon (LC, WEOC). Moreover, humification indexes (HR, HI, DP) were determined. The amounts of macro- and micronutrients, OM, TOC, LC, WEOC were greater for vermicomposts. Regardless of these differences, both vermicomposts and composts were characterized by considerable amounts of organic matter ranging from 325 to 631 g·kg−1 and TOC amounting from 82 to 270 g·kg−1. Moreover, the tested organic fertilizers were characterized by high contents of N (7–21.5 g·kg−1), K (3.7–24.4 g·kg−1), Ca (12.2–44.0 g·kg−1), Fe (133.1–333.8 mg·kg−1) and Mn (71.5–113.8 mg·kg−1). The analyzed VCs and Cs did not exceed the permissible amounts of heavy metals (Cr, Pb) and contained a comparable amount and quality of humus compounds. The level of CHS ranged from 29.6 to 41 g·kg−1 for vermicomposts, and from 19.8 to 51.8 g·kg−1 for composts. The humification indexes indicate that VCs and Cs were well–matured despite different composting conditions. The HI values for VCs ranged from 8.3% to 10% and for Cs amounted from 12.2% to 16.8%. Similarly, the HR values were higher for composts (24.3–33%) in comparison to VCs (15.2–20.1%). Vermicomposting and composting of biowaste is economically and environmentally justified. Fertilizers obtained in the composting process are a valuable source of organic material and nutrients essential for plants and can be safely used in private gardens.

Environmental impacts of the widespread use of chlorine-based disinfectants during the COVID-19 pandemic.

Chlorinated disinfectants are widely used in hospitals, COVID-19 quarantine facilities, households, institutes, and public areas to combat the spread of the novel coronavirus as they are effective against viruses on various surfaces. Medical facilities have enhanced their routine disinfection of indoors, premises, and in-house sewage. Besides questioning the efficiency of these compounds in combating coronavirus, the impacts of these excessive disinfection efforts have not been discussed anywhere. The impacts of chlorine-based disinfectants on both environment and human health are reviewed in this paper. Chlorine in molecular and in compound forms is known to pose many health hazards. Hypochlorite addition to soil can increase chlorine/chloride concentration, which can be fatal to plant species if exposed. When chlorine compounds reach the sewer/drainage system and are exposed to aqueous media such as wastewater, many disinfection by-products (DBPs) can be formed depending on the concentrations of natural organic matter, inorganics, and anthropogenic pollutants present. Chlorination of hospital wastewater can also produce toxic drug-derived disinfection by-products. Many DBPs are carcinogenic to humans, and some of them are cytotoxic, genotoxic, and mutagenic. DBPs can be harmful to the flora and fauna of the receiving water body and may have adverse effects on microorganisms and plankton present in these ecosystems.

The role of soil in saving human race from COVID-19 pandemic. (Special Issue: October 2021.)

Soil is the most complex part of land as its contents are made of all the other key components of land namely geology (soil minerals), hydrology (soil water), atmosphere (soil air), and organisms including man (soil organic matter including dead bodies). This is why the functions of the soil are not only numerous but also indispensable. Among the functions, the role of the soil in sustaining human life remains unimaginable. Over 3.8 million people have been killed by COVID-19 by June 15, 2021 in the world and more are still dying. Some unrecorded millions died of hunger as a result of the lockdown during the peak of COVID-19 pandemic. Where are these dead bodies and materials associated with those that died of COVID-19? Where did all the food palliatives (rice, maize, wheat, yam, gari, vegetable oil, etc.) come from? The human body is composed of approximately 64% water, 20% protein, 10% fat, 1% carbohydrate, 5% minerals. When decomposed these various components result to various gaseous compounds and residues that are harmful to human life and environment. When dead bodies are buried human health and environment are saved. The dead bodies, the wastes and their contents are in the soil providing "palliatives" to soil microorganisms while protecting the remaining human population and the environment. Cremation products also end up in the soil. The soil also provided and still provides the food palliatives. Thus, the soil is our number one saviour against COVID-19 pandemic and can be adjudged as the saviour of the human race to date. Coincidentally man was made from the soil and must return to the soil. Key words: soil functions, burial, cremation, palliatives, COVID-19.

Water quality assessment of the Ganges River during COVID-19 lockdown.

Ganges River water quality was assessed to record the changes due to the nation-wide pandemic lockdown. Satellite-based (Sentinel-2) water quality analysis before and during lockdown was performed for seven selected locations spread across the entire stretch of the Ganges (Rishikesh-Dimond Harbour). Results revealed that due to the lockdown, the water quality of the Ganges improved with reference to specific water quality parameters, but the improvements were region specific. Along the entire stretch of Ganges, only the Haridwar site showed improvement to an extent of being potable as per the threshold set by the Central Pollution Control Board, New Delhi, India. A 55% decline in turbidity at that site during the lockdown was attributed to the abrupt halt in pilgrimage activities. Absorption by chromophoric dissolved organic matter which is an indicator of organic pollution declined all along the Ganges stretch with a maximum decline at the downstream location of Diamond Harbour. Restricted discharge of industrial effluent, urban pollution, sewage from hotels, lodges, and spiritual dwellings along the Ganges are some of the reasons behind such declines. No significant change in the geographic trend of chlorophyll-a was observed. The findings of this study highlight the importance of regular monitoring of the changes in the Ganges water quality using Sentinel-2 data to further isolate the anthropogenic impact, as India continues the phase-wise opening amidst the pandemic.

Determining the environmental and atmospheric effects of coronavirus disease 2019 (COVID-19) quarantining by studying the total aerosol optical depth, black carbon, organic matter, and sulfate in Blida City of Algeria.

BACKGROUND: To study, estimate and discuss the variations of the aerosol optical depth (AOD), black carbon, sulfate and organic matter, in the atmosphere in Blida City of Algeria, which was greatly affected by COVID-19 pandemic. METHODS: We analyzed the effects of changes in the total AOD, black carbon, sulfate, and organic matter in the atmosphere (λ = 550 nm) in the same period of 2019 and 2020, following the COVID-19 epidemic in Blida City, which was the most-affected city in Algeria. RESULTS: The quarantine that was enacted to limit the spread of COVID-19 resulted in side effects that were identifiable in the total AOD and in some of its atmospheric components. Comparing these variables in 2019 and 2020 (in the months during the quarantine) revealed that in April, the BCAOD values were much lower in 2020 than in 2019. CONCLUSION: Based on the effects of the emerging COVID-19, the research listed the changes received from the AOD, and is considered as a comparative study and represents a significant side effect of the quarantine that was mainly designed to limit COVID-19.